物理學院“博約學術(shù)論壇”系列報告第 113 期
題目:Nonplanar aromatic molecules at surfaces: self-assembly, spin filtering and molecular motors
報告人:Prof. Dr. Karl-Heinz Ernst(Empa, Swiss Federal Laboratories for Materials Science and Technology, Switzerland)
時 間:2017年7月10日(周一)上午10:00
地 點:北京理工大學 中心教學樓610
Abstract:
Molecular recognition among chiral molecules on surfaces is of paramount importance in biomineralization, enantioselective heterogeneous catalysis, and for the separation of chiral molecules into their two mirror-image isomers (enantiomers) via crystallization or chromatography. Understanding the principles of molecular recognition in general, however, is a difficult task and calls for investigation of appropriate model systems. One popular approach is thereby studying intermolecular interactions on well-defined solid surfaces, which allows in particular the use of scanning tunneling microscopy (STM). Examples of chiral amplification via the so-called ‘sergeant-and-soldiers’ effect as well as manipulation of chiral adsorbates via inelastic electron tunneling will be presented. In a Pasteur-type experiment at the nanoscale, molecules that constitute a dimer are spatially separated with a molecular STM tip and their absolute handedness is determined with submolecular resolution STM. Moreover, we report spin-dependent filtering of electrons by monolayers of these helical molecules. Finally the first successful electrical current- driven, unidirectional motion of a synthetic molecule will be presented.
簡歷:
Karl-Heinz Ernst,,瑞士聯(lián)邦材料科學與技術(shù)實驗室高級科學家,蘇黎世大學教授,。1990年德國柏林自由大學獲博士學位,1992年加入瑞士聯(lián)邦材料科學與技術(shù)實驗室,。曾為美國華盛頓大學,、德國柏林自由大學、美國IBM實驗室(Almaden?)訪問學者,。 長期從事有機功能分子在固體表面的自組裝結(jié)構(gòu)和物性調(diào)控研究,,在手性識別和分離、有機納米機器等方面取得了一系列創(chuàng)造性成果,,其有機納米馬達相關成果曾被2016年諾貝爾化學獎評審委員會在公布獲獎人名單時提及,。在Nature、Nature chemistry,、PRL,、JACS、Angew. Chem.,、NanoLett.等期刊發(fā)表論文130多篇,,他引3500多次,h-index為35,。在國際學術(shù)會議上作邀請報告200多次,。先后擔任CHIMIA ?、Surface Science ?,、Helvetica Chimica Acta 等學術(shù)期刊編委,,并曾多次組織和主持國際學術(shù)會議。
聯(lián)系方式:物理學院辦公室 (68913163)
邀請人:肖文德